A non-Newtonian fluid is a fluid whose flow properties are not described by a single constant value of viscosity. Many polymer solutions and molten polymers are non-Newtonian fluids, as are many commonly found substances such as ketchup, starch suspensions, paint, blood and shampoo. In a Newtonian fluid, the relation between the shear stress and the strain rate is linear (and if one were to plot this relationship, it would pass through the origin), the constant of proportionality being the coefficient of viscosity. In a non-Newtonian fluid, the relation between the shear stress and the strain rate is nonlinear, and can even be time-dependent. Therefore a constant coefficient of viscosity cannot be defined. A ratio between shear stress and rate of strain (or shear-dependent viscosity) can be defined, this concept being more useful for fluids without time-dependent behavior.

Although the concept of viscosity is commonly used to characterize a material, it can be inadequate to describe the mechanical behavior of a substance, particularly non-Newtonian fluids. They are best studied through several other rheological properties which relate the relations between the stress and strain rate tensors under many different flow conditions, such as oscillatory shear, or extensional flow which are measured using different devices or rheometers. The properties are better studied using tensor-valued constitutive equations, which are common in the field of continuum mechanics.

## Nessun commento:

## Posta un commento